Chemistry Letters · 1997 · 16 citations · 8 references
Natural SciencesChemistryOrganic ChemistryOrganometallic ChemistryStructure-activity RelationshipsCoordination ChemistryRadical ReactionsRedox ChemistryRedox ReactionsFree Radical SubstitutionRadical MechanismsRadical Substitution ReactionsRadical-radical Reactions
Abstract The reaction of (η5-cyclopentadienyl)(1,2-ethenedithiolato)cobalt(III) complexes with dibenzoyl peroxide at moderate temperature (40 °C) brings about the substitution of a benzoyloxy group for a hydrogen in the cobaltadithiolene ring in an ionic mechanism. At 110 °C in a toluene solution, the substitution of a benzyl group for a hydrogen in the cobaltadithiolene ring in a radical mechanism occurs competitively with benzoyloxylation.
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