Concepedia

Molecular Structure of a Cyclopropyl Substituted Vinyl Cation

Andrea Klaer, Wolfgang Saak, Detlev Haase, Thomas Müller

Journal of the American Chemical Society · 2008 · 34 citations · 15 references

DOI

Concepts

Abstract

The experimentally determined molecular structure of vinyl cation 1 provides clear evidence for the occurrence of extended sigma-conjugation involving the cyclopropyl ring and the beta-C-Si bonds.

References

15

Modern physical organic chemistry

Choice Reviews Online · 2006 · 2.4K citations

, , +17

Harmonic Vibrational Frequencies:  Scaling Factors for HF, B3LYP, and MP2 Methods in Combination with Correlation Consistent Basis Sets

Pankaj Sinha, Scott E. Boesch, Changming Gu et al. · The Journal of Physical Chemistry A · 2004 · 466 citations

, , +14

The X‐ray Structure of a Vinyl Cation

Thomas Müller, Christopher A. Reed · Angewandte Chemie International Edition · 2004 · 107 citations · Full text

, , +9

Unusually Stable Vinyl Cations

Thomas Müller, Rita Meyer, Dirk Lennartz et al. · Angewandte Chemie International Edition · 2000 · 82 citations

, , +11

NMR spectroscopic and computational characterization of 1-(p-anisyl)vinyl cations. Methoxy group rotation as a probe of .beta.-carbon-silicon, .beta.-carbon-carbon and .beta.-carbon-hydrogen hyperconjugation

Hans Ullrich Siehl, Frank Peter Kaufmann, Kenzi Hori · Journal of the American Chemical Society · 1992 · 78 citations

, , +9