Z-contrast imaging of the arrangement of Cu in precipitates in 6XXX-series aluminium alloys

Abstract

Abstract High-resolution annular dark field imaging has been used to study small precipitates in the Al matrix of 6XXX-series aluminium alloys. Cu-containing columns in precipitates were imaged by atomic number contrast along a 〈100〉 matrix direction. At an under-aged condition, large, lath-shaped particles of the Cu-containing Q′-phase were observed at grain boundaries. At over-aged conditions, Q′ was the main matrix phase. In both cases the laths showed an Al {150} habit plane. A precursor phase was found, with different arrangement of Cu-rich columns from that of the Q′-phase and sharing Al {100} habit planes. Precipitates containing elements of both the Q′-phase and the precursor were found to be common. Annular dark field imaging can differentiate directly between phases. The method complements and aids interpretation of conventional high-resolution TEM images and nano beam diffraction observations. The results obtained contribute to an improved understanding of the crystallography of the precursor and details of the structural transformation taking place during the precipitation process. Acknowledgements HSH, ATJH, JCW acknowledge financing from the Norwegian Research Council through the SUP programme ‘Micro- and nanostructural materials development’. SJA and CDM are funded through the NorLight programme “Heat treatment fundamentals”, financed through industry and the Norwegian Research Council. The industrial sponsors are Hydro Aluminium AS and Elkem Aluminium. The authors would like to thank Heimir Magnusson for excellent maintenance of the TEM facilities.