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Remarkable cumulative stereoselectivity in cyclopropanation with supramolecular Cu(i) catalytic complexes
12
Citations
7
References
2000
Year
Chemical EngineeringNovel OrganocatalystsEngineeringAlkene MetathesisCoordination ComplexRemarkable Cumulative StereoselectivityHighest DiastereoselectivitiesOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryMolecular ComplexAsymmetric CatalysisEthyl DiazoacetateSupramolecular Cu
Supramolecular Cu(I) catalyst 1 exhibited 77% cumulative (dia- and enantio-) stereoselectivity and one of the highest diastereoselectivities (86% de) obtained to date in the cyclopropanation of styrene with ethyl diazoacetate.
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