Pure and Applied Chemistry · 2009 · 80 citations · 3 references
Natural SciencesChemical EngineeringChemistryElectrochemistryInterface ScienceSurface ChemistryCharge Transfer ReactionsElectrode-electrolyte InterfacesElectrolyte SolutionsInterfacial ElectrochemistryIon-conducting MaterialsSurface ChargeCharge Distribution At InterfacesCharge Exchange ProcessesCharge Transfer KineticsExperimental Results InterpretationIon-water InteractionsIonic Liquid ElectrolytesIonic Liquid ExtractionIonic Transport
This article provides a brief review of theoretical and methodological concepts in the area of the charge-transfer processes at the interface between a hydrophobic ionic liquid (IL) and an electrolyte solution in water (W). Electrochemical methods of study of the W|IL interfaces are described, current experimental problems are indicated, and the most important experimental results are summarized. The relevance of electrochemistry at the W|IL interfaces to the extraction behavior of ILs is outlined.
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