Reactions of bis(trimethylsilyl)bromomethyllithium and tris(trimethylsilyl)methyllithium. the synthesis of α-bromovinylsilanes

A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)

E. J. Corey, P.L. Fuchs · Tetrahedron Letters · 1972 · 1.6K citations

Natural Sciences, Chemical Engineering, Chemistry +7

Carbonyl olefination reaction using silyl-substituted organometallic compounds

Donald J. Peterson · The Journal of Organic Chemistry · 1968 · 795 citations

Natural Sciences, Chemistry, Analytical Chemistry +8

[Tris(trimethylsilyl)methyl]lithium: An alkyllithium compound of unusual stability

M. A. COOK, Colin Eaborn, A.E. Jukes et al. · Journal of Organometallic Chemistry · 1970 · 112 citations

Natural Sciences, Chemistry, Materials Science +5

Halomethyl-metal compounds

Dietmar Seyferth, Robert L. Lambert, Earle Marie Hanson · Journal of Organometallic Chemistry · 1970 · 94 citations

.alpha.-Chloro-.alpha.-trimethylsilyl carbanion, a reagent for homologation of ketones and aldehydes via .alpha.,.beta.-epoxysilanes

Cliff Burford, Frank Cooke, Ed Ehlinger et al. · Journal of the American Chemical Society · 1977 · 86 citations

Natural Sciences, Chemistry, Catalysis +6