Advanced Materials · 1990 · 312 citations · 39 references
Natural SciencesChemistryMaterials ScienceElectrochemistryPolymer ChemistrySensorsConducting PolymersConductive PolymersIon-conducting MaterialsIonic ConductivityIonic ConductorsPolymer PhysicsConductivity In PolymersElectrolytesEnergy Storage ApplicationsIon-conducting PolymersIonic Conductivity In PolymersIonic Transport In PolymersPolyethylene OxidePolymer Electrolytes
A solvation‐desolvation mechanism (see figure) is responsible for ionic conductivity in polymers such as polyethylene oxide. The solvating sites are covalently linked through flexible bonds meaning that a net displacement of the ligand with the ions over macroscopic distances is forbidden, a situation intermediate between liquids and solids. Sensors, batteries, and displays are among the applications of these polymeric electrolytes. equation image
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Electrical conductivity in ionic complexes of poly(ethylene oxide)
Peter V. Wright · British Polymer Journal · 1975 · 1.3K citations
Natural Sciences, Chemistry, Physics +17