Concepedia

Formation of a gallium triphosphorus heterocycle by reaction of the alkylgallium(I) compound Ga4[C(SiMe3)3]4 with tri(tert-butyl)cyclotriphosphane

Werner Uhl, Maike Benter

Journal of the Chemical Society Dalton Transactions · 2000 · 19 citations · 22 references

DOI

Concepts

Abstract

Tri(tert-butyl)cyclotriphosphane reacted with Ga4[C(SiMe3)3]41 by the insertion of a monomeric GaR fragment into one of its P–P bonds. A four-membered, slightly folded GaP3 heterocycle was formed which has a co-ordinatively unsaturated gallium atom and all substituents in trans positions.

References

22

The Tetrameric Aluminum(<scp>I</scp>) Compound [{Al(η<sup>5</sup>‐C<sub>5</sub>Me<sub>5</sub>)}<sub>4</sub>]

Carsten Dohmeier, Christian Robl, Matthias Tacke et al. · Angewandte Chemie International Edition in English · 1991 · 389 citations

, , +10

Single‐Source III/V Precursors: A New Approach to Gallium Arsenide and Related Semiconductors

Alan H. Cowley, Richard A. Jones · Angewandte Chemie International Edition in English · 1989 · 299 citations

, , +25

A Simple Synthesis of [(Cp<sup>*</sup>Al)<sub>4</sub>] and Its Conversion to the Heterocubanes [(Cp<sup>*</sup>AlSe)<sub>4</sub>] and [(Cp<sup>*</sup>AlTe)<sub>4</sub>] (Cp<sup>*</sup> = η<sup>5</sup>‐C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)

Stephan Schulz, Herbert W. Roesky, Hans Joachim Koch et al. · Angewandte Chemie International Edition in English · 1993 · 197 citations · Full text

[Ga<sub>4</sub>{C(SiMe<sub>3</sub>)<sub>3</sub>}<sub>4</sub>] with a Tetrahedral Ga<sub>4</sub> Skeleton

Werner Uhl, Wolfgang Hiller, Marcus Layh et al. · Angewandte Chemie International Edition in English · 1992 · 169 citations

, , +7

Three-membered phosphorus ring compounds

Marianne Bäudler · Pure and Applied Chemistry · 1980 · 136 citations · Full text

, , +3