Heterometal‐Embedded Organic Conjugate Frameworks from Alternating Monomeric Iron and Cobalt Metalloporphyrins and Their Application in Design of Porous Carbon Catalysts

Abstract

The use of an alternately conjugated networking method to prepare the first porous heterometalloporphyrinic frameworks with ordered alternation of Fe and Co moieties is presented. Subsequent carbonization gives an Fe and Co co-embedded porous carbon composite with a very high activity and remarkable electrochemical stability for oxygen reduction reaction in both alkaline and acidic electrolytes. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.