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Phosphane‐Free Palladium‐Catalyzed Carbonylative Suzuki Coupling Reaction of Aryl and Heteroaryl Iodides
63
Citations
13
References
2009
Year
Arylboronic AcidChemical EngineeringCross-coupling ReactionEngineeringCarbonylative Cross‐coupling ReactionNatural SciencesDiversity-oriented SynthesisVarious ArylCatalytic SynthesisHeteroaryl IodidesOrganic ChemistryOrganometallic CatalysisCatalysisChemistryBiomolecular Engineering
Abstract The carbonylative cross‐coupling reaction of an arylboronic acid with an aryl iodide and a heteroaryl iodide to give unsymmetrical biaryl ketones was carried out by using Pd(tmhd) 2 /Pd(OAc) 2 as a phosphane‐free catalyst. Various aryl and heteroaryl iodides with different arylboronic acid derivatives provided good to excellent yields of the desired products under optimized reaction conditions.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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