Concepedia

Direct multiple C–H bond arylation reaction of heteroarenes catalyzed by cationic palladium complex bearing 1,10-phenanthroline

Fumitoshi Shibahara, Eiji Yamaguchi, Toshiaki Murai

Chemical Communications · 2010 · 194 citations · 37 references

DOI

Abstract

A cationic palladium complex bearing 1,10-phenanthroline ligand is found to catalyze direct C-H arylation reactions of heteroarenes with aryl iodides to give mono-, di-, or tri-arylated products selectively.

References

37

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

Serge I. Gorelsky, David Lapointe, Keith Fagnou · Journal of the American Chemical Society · 2008 · 995 citations

Palladium-Catalyzed Benzene Arylation:  Incorporation of Catalytic Pivalic Acid as a Proton Shuttle and a Key Element in Catalyst Design

Marc Lafrance, Keith Fagnou · Journal of the American Chemical Society · 2006 · 983 citations

Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions

Robert J. Phipps, Neil P. Grimster, Matthew J. Gaunt · Journal of the American Chemical Society · 2008 · 789 citations

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Dipannita Kalyani, Nicholas R. Deprez, Lopa V. Desai et al. · Journal of the American Chemical Society · 2005 · 788 citations

Catalytic Direct Arylation with Aryl Chlorides, Bromides, and Iodides:  Intramolecular Studies Leading to New Intermolecular Reactions

Louis‐Charles Campeau, Mathieu Parisien, Annie Jean et al. · Journal of the American Chemical Society · 2005 · 674 citations