Concepedia

ALLYLSILANES AS SYNTHETIC INTERMEDIATES. II. SYNTHESES OF HOMOALLYL ETHERS FROM ALLYLSILANES AND ACETALS PROMOTED BY TITANIUM TETRACHLORIDE

Akíra Hosomi, Masahiko Endo, Hideki Sakurai

Chemistry Letters · 1976 · 190 citations · 1 references

DOI

Concepts

Abstract

Abstract The reaction of allylsilanes with acetals in the presence of titanium tetrachloride afforded homoallyl ethers in good yields. The reaction took place regiospecifically with transposition of the allyl group.

References

1

The major reducing species operative when an equimolar proportion of AlCl<sub>3</sub> is added over a short period of time to an ether solution of equimolar proportions of LiAlH<sub>4</sub> and acetal or ketal

U. E. Diner, H. A. Davis, R. K. Brown · Canadian Journal of Chemistry · 1967 · 17 citations

, , +9