Concepedia

Rhodium(<scp>ii</scp>)-catalysed tandem aziridination and ring-opening: stereoselective synthesis of functionalised tetrahydrofurans

William P. Unsworth, Nicola Clark, Thomas O. Ronson, Kiri Stevens, Amber L. Thompson, Scott G. Lamont, Jeremy Robertson

Chemical Communications · 2014 · 15 citations · 29 references

DOI

Concepts

Abstract

Aziridines formed upon treatment of allylic carbamates and homoallylic sulfamates with Rh(II) carboxylate catalysts under oxidative conditions are trapped by suitably-disposed hydroxyl groups to give functionalised tetrahydrofurans.

References

29

<i>SUPERFLIP</i>– a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions

Lukáš Palatinus, G. Chapuis · Journal of Applied Crystallography · 2007 · 4.2K citations · Full text

, , +16

<i>CRYSTALS</i>version 12: software for guided crystal structure analysis

P. W. Betteridge, J. R. Carruthers, Richard I. Cooper et al. · Journal of Applied Crystallography · 2003 · 2.7K citations

, , +16

Catalytic Asymmetric Aminohydroxylation (AA) of Olefins

Guigen Li, Han‐Ting Chang, K. Barry Sharpless · Angewandte Chemie International Edition in English · 1996 · 687 citations

, , +9

A Rh-Catalyzed C−H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones

Christine G. Espino, J. Du Bois · Angewandte Chemie International Edition · 2001 · 468 citations

, , +4

Nitrene Chemistry in Organic Synthesis: Still in Its Infancy?

Geoffroy Dequirez, Valérie Pons, Philippe Dauban · Angewandte Chemie International Edition · 2012 · 468 citations

, , +9