Proline-functionalised calix[4]arene: an anion-triggered hydrogelator

Thomas Becker, Ching Yong Goh, Franca Jones, Matthew J. McIldowie, Mauro Mocerino, Mark I. Ogden

Chemical Communications · 2008 · 104 citations · 20 references

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Abstract

A water-soluble, chiral calix[4]arene has been found to form hydrogels when triggered by the presence of specific anions, with efficacy linked to the Hofmeister series; the gel properties are modified by the associated cations, and gelation can be reversibly switched off by increasing pH.

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