Enantioselective Polyol Synthesis via the Cope Rearrangement of Chiral Aldol Products. A Synthesis of the C1-C10-Fragment of Nystatin A1

Chiral synthesis via organoboranes. 27. Remarkably rapid and exceptionally enantioselective (approaching 100% ee) allylboration of representative aldehydes at -100.degree. under new, salt-free conditions

Uday S. Racherla, Herbert C. Brown · The Journal of Organic Chemistry · 1991 · 357 citations

Natural Sciences, Chemistry, Catalysis +6

Synthesis of the cyclic hexapeptide echinocandin D. New approaches to the asymmetric synthesis of .beta.-hydroxy .alpha.-amino acids

David A. Evans, Ann E. Weber · Journal of the American Chemical Society · 1987 · 197 citations

Natural Sciences, Biochemistry, Chemistry +11

Diastereoselective synthesis of protected syn 1,3-diols by base-catalyzed intramolecular conjugate addition of hemiacetal-derived alkoxide nucleophiles

David A. Evans, Joelle A. Gauchet-Prunet · The Journal of Organic Chemistry · 1993 · 165 citations

Natural Sciences, Chemistry, Biocatalysis +5

Aldol addition reactions of chiral crotonate imides

David A. Evans, Eric B. Sjogren, Javier Bartrolí et al. · Tetrahedron Letters · 1986 · 125 citations

Natural Sciences, Biochemistry, Chemistry +6

Tandem-Bisalkylation of 2-Trialkylsilyl-1,3-dithiane: A New Sequential Transformation for the Synthesis of C₂-Symmetrical Enantiopure 1,5-Diols and β,β′-Dihydroxyketones as well as of Enantiopure 1,3,5-Triols

Lutz‐F. Tietze, Jan‐Arne Gewert, U. Jakobi · Synlett · 1994 · 106 citations

Natural Sciences, Chemistry, Organic Chemistry +10