Concepedia

9‐Fluorenylidene‐2,2,6,6‐tetramethylpiperidinoborane: an Allene Isoester with Two‐Coordinated Boron and BC Double Bond

Bernhard Glaser, Heinrich Nöth

Angewandte Chemie International Edition in English · 1985 · 112 citations · 10 references

DOI

Concepts

Abstract

In the 1-aza-2-boraallene 1, the bulky substitutents are responsible for the kinetic stability of the NBC system. Structural proof is provided by, among other things, its reaction with azides to give azaboriranes.

References

10

Generation of boron-stabilized carbanions

Michael W. Rathke, Ronald Kow · Journal of the American Chemical Society · 1972 · 165 citations

, , +6

A Boron‐Carbon Double Bond

Hartmut Klusik, Armin Berndt · Angewandte Chemie International Edition in English · 1983 · 149 citations

, , +6

Beiträge zur Chemie des Bors, 137 [1]. Über eine einfache Synthese eines Amino-imino-borans und seiner Addukte mit Bortrichlorid und Bortribromid / Contribution to the Chemistry of Boron, 137 [1]. A Convenient Synthesis of an Amino-Imino-Borane and its Adducts with Boron Trichloride and Boron Tribromide

Heinrich Nöth · Zeitschrift für Naturforschung B · 1983 · 91 citations · Full text

, , +8

Contributions to the chemistry of boron. 121. Dicoordinate amidoboron cations

H. Noeth, Rudolf Staudigl, Hans Wagner · Inorganic Chemistry · 1982 · 80 citations

, , +6

The dimesitylboron group in organic synthesis. 4. The ‘boron Wittig’ reaction

Andrew Pelter, Bakthan Singaram, John Wilson · Tetrahedron Letters · 1983 · 68 citations

, , +7