Reviews of Modern Physics · 2009 · 495 citations · 197 references
Natural SciencesChemistryPhysicsCondensed Matter PhysicsPhysical ChemistrySolid-state ChemistryAb Initio MethodsActinide ChemistryExchange InteractionsIntermolecular InteractionsMolecular InteractionsStrongly Correlated Electron SystemsActinide BondingActinide Electronic StructureCrystal Field Theory Of ActinidesCubic LatticesDelocalized Electron SystemsElectron-electron InteractionsSimple Cubic LatticeTwo-dimensional Electron Systems
This article reviews the physics of multipolar interactions and multipolar order in $f$-electron systems, using the actinide dioxides as a paradigm. In the past few years, these apparently simple cubic compounds have been studied intensively, and many new phenomena have been discovered. Here the experimental results are discussed together with the current theoretical understanding of multipolar interactions.
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