Concepedia

Reductive N−N Bond Cleavage of Diphenylhydrazine and Azobenzene Induced by Coordinatively Unsaturated Cp*Fe{N(SiMe<sub>3</sub>)<sub>2</sub>}

Yasuhiro Ohki, Yuko Takikawa, Tsubasa Hatanaka, Kazuyuki Tatsumi

Organometallics · 2006 · 49 citations · 22 references

DOI

Concepts

Abstract

The coordinatively unsaturated iron(II) amido complex Cp*Fe{N(SiMe 3 ) 2 } ( 1 ) serves as an efficient precursor for the cleavage of the N−N bond of diphenylhydrazine. The N N bond of azobenzene was also found to be activated by 1 in the presence of pinacolborane.

References

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