Macromolecular Rapid Communications · 1995 · 116 citations · 26 references
Natural SciencesMaterials EngineeringMaterials ScienceBiomaterialsPolymer ChemistryPolymer MaterialsBiological OscillationsGelsHydrogelsOscillatory RheologyPolymer PhysicsPolymeric BiomaterialsGel MechanicsHydrogel MaterialsHydrogel Swelling BehaviorMechanical Properties Of GelsNonlinear Reaction DynamicsPh-sensitive HydrogelsPolymer GelsThermo-responsive Hydrogels
Abstract Novel gel systems demonstrating rhythmically pulsatile mechanical motion similar to that of a heartbeat were developed. Self‐oscillations of swelling and deswelling for the polymer hydrogels were realized by coupling pH and temperature sensitive hydrogels with a non‐linear chemical reaction in the external solution media. The novel gel dynamics exhibiting cyclic and rhythmical oscillations may establish a new concept for functional materials that work under dynamic oscillating states.
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Volume phase transition in a nonionic gel
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Natural Sciences, Materials Engineering, Materials Science +12
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