Concepedia

Synthesis of Disubstituted Phosphinates <i>via</i> Palladium‐Catalyzed Hydrophosphinylation of <i>H</i>‐Phosphinic Acids

Christelle Petit, Fabien Fécourt, Jean‐Luc Montchamp

Advanced Synthesis & Catalysis · 2011 · 29 citations · 39 references

DOI

Concepts

Abstract

Abstract The first metal‐catalyzed hydrophosphinylation of unsaturated hydrocarbons with H ‐phosphinic acids is described. A strategy to activate the PH bond through control of the tautomeric equilibrium using ethylene glycol is described. The reactions also avoid chromatographic purification.

References

39

Efficient and Selective Nickel-Catalyzed Addition of H−P(O) and H−S Bonds to Alkynes

Li‐Biao Han, Chen Zhang, Hideaki Yazawa et al. · Journal of the American Chemical Society · 2004 · 252 citations

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Recent Developments in the Addition of Phosphinylidene‐Containing Compounds to Unactivated Unsaturated Hydrocarbons: Phosphorus–Carbon Bond Formation by Hydrophosphinylation and Related Processes

Laëtitia Coudray, Jean‐Luc Montchamp · European Journal of Organic Chemistry · 2008 · 199 citations · Full text

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Triethylborane-Initiated Room Temperature Radical Addition of Hypophosphites to Olefins:  Synthesis of Monosubstituted Phosphinic Acids and Esters

Sylvine Deprèle, Jean‐Luc Montchamp · The Journal of Organic Chemistry · 2001 · 155 citations

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Hydrophosphination of Unactivated Alkenes, Dienes and Alkynes: A Versatile and Valuable Approach for the Synthesis of Phosphines

Olivier Delacroix, Annie−Claude Gaumont · Current Organic Chemistry · 2005 · 148 citations

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Metal-catalyzed additions of H–P(O) bonds to carbon–carbon unsaturated bonds

Qing Xu, Li‐Biao Han · Journal of Organometallic Chemistry · 2010 · 143 citations

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