Bulletin of the Chemical Society of Japan · 1993 · 20 citations · 6 references
Materials ScienceChemical EngineeringLong Perfluoroalkyl GroupEngineeringGood PhotostabilityTheir ApplicationFluorous SynthesisOrganic ChemistryChemistryMolecule-based MaterialPhotochromism
Abstract New fluorine-containing azopyridone dyes, 3-cyano-6-hydroxy-5-[2-(perfluoroalkyl)phenylazo]-2-pyridones, have been synthesized. Though the introduction of a long perfluoroalkyl group lowered film forming ability and sensitivity, 5-[2-(trifluoromethyl)phenylazo]- and 5-[2-(perfluorobutyl)phenylazo]-3-cyano-4-methyl-6-hydroxy-2-pyridones showed good photostability.
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