Concepedia

The stabilisation of water as a ligand in lithiated organic compounds: intra- and inter-molecular hydrogen bonding in the structures of the aquo complexes [Li·HMPA·H2O]2 and [Li·HMPA]2·H2O

David R. Armstrong, Donald Barr, Paul R. Raithby, Ronald Snaith, Dominic S. Wright, Paul von Ragué Schleyer

Inorganica Chimica Acta · 1991 · 30 citations · 9 references

DOI

Concepts

References

9

Self—Consistent Molecular Orbital Methods. XII. Further Extensions of Gaussian—Type Basis Sets for Use in Molecular Orbital Studies of Organic Molecules

Warren J. Hehre, R. Ditchfield, John A. Pople · The Journal of Chemical Physics · 1972 · 15.8K citations

, , +16

The influence of polarization functions on molecular orbital hydrogenation energies

P. C. Hariharan, John A. Pople · Theoretical Chemistry Accounts · 1973 · 15.7K citations

, , +14

Hydrogen Bonding in Solids

G. Wilkinson · Physics Bulletin · 1968 · 722 citations

, , +13

A unique lithium halide complex, [(LiBr)<sub>2</sub>·3HMPA·toluene]: synthesis from reaction of solid NH<sub>4</sub>Br with Bu<sup>n</sup>Li in HMPA (hexamethylphosphoramide)/toluene media, crystal structure showing two Li–Br units linked by three µ<sub>2</sub>-HMPA ligands, and detection of<sup>7</sup>Li ⋯<sup>31</sup>P coupling in solutions of the complex

Donald Barr, Michael J. Doyle, Robert E. Mulvey et al. · Journal of the Chemical Society Chemical Communications · 1989 · 42 citations

, , +11

The first lithiated organic compound containing water as a ligand: synthesis and crystal structure of 2-mercaptobenzoxazolyl(tetramethylethylenediamine)lithium monohydrate, C<sub>6</sub>H<sub>4</sub>OC(S)NLi(tmeda)H<sub>2</sub>O, a model acid–base intermediate

Donald Barr, Paul R. Raithby, Paul von Ragué Schleyer et al. · Journal of the Chemical Society Chemical Communications · 1990 · 41 citations

, , +10