Publication | Closed Access
APPLICATION OF ASYMMETRIC [2,3]WITTIG REARRANGEMENT TO STEREOCONTROL OVER THREE CONTIGUOUS CHIRAL CENTERS. A NEW SYNTHESIS OF (+)-BLASTMYCINONE
22
Citations
6
References
1985
Year
Asymmetric CatalysisDiversity Oriented SynthesisEngineeringα-Hydroxy KetoneNatural SciencesDiversity-oriented SynthesisMolecular BiologyZinc BorohydrideOrganic ChemistryNew Synthesis OfNew SynthesisStereoselective SynthesisNatural Product SynthesisRadiation OncologySynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract A new synthesis of (+)-blastmycinone is described which relies on the combination of the asymmetric [2,3]Wittig rearrangement with the selective reduction of an α-hydroxy ketone with zinc borohydride.
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