Thiolate complexes of osmium(III) with tertiary phosphines and their dicarbonyl derivatives of osmium(II): X-ray crystal structure of trans,trans,trans-[Os(SC6F5)2(CO)2(PEt2Ph)2]

Abstract

The preparation and physical properties of complexes of the type [Os(SC6F5)3(PR3)2] and [Os(SC6F5)2(CO)2(PR3)2](PR3= PMe2Ph, PMePh2, PEt2Ph, or PEtPh2), and the X-ray structure of trans,trans,trans-[Os(SC6F5)2(CO)2(PEt2Ph)2] are described.