Angewandte Chemie International Edition · 2007 · 638 citations · 28 references
Natural SciencesChemical EngineeringMaterials ScienceCatalysisEnergy MaterialsReaction EngineeringCatalyst DesignCatalyst SynthesisCatalytic MaterialsCatalytic Reaction EngineeringFuel Cell MaterialsFuel CellsAmmonia FuelCatalytic Energy ConversionFuel Cell CatalystsHydrogen FuelHydrogen Fuel CellsMetal CatalystsMild Reaction ConditionsSupported Acid Catalysts
The B all and N all? Ammonia–borane (AB, H3NBH3) contains 19.6 weight % H, and is one of the materials currently being examined as a possible H2 source for use in fuel cells to power automobiles. Challenges for this technology are noted, and recent advances, especially in the development of both transition-metal and acid catalysts which promote H2 release from AB under mild conditions, are highlighted.
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Reversible, Metal-Free Hydrogen Activation
Gregory C. Welch, Ronan R. San Juan, Jason D. Masuda et al. · Science · 2006 · 2.1K citations
G. W. Crabtree, M. S. Dresselhaus, Michelle V. Buchanan · Physics Today · 2004 · 1.6K citations · Full text