Bulletin of the Chemical Society of Japan · 1956 · 26 citations · 5 references
Natural SciencesChemical EngineeringChemistryChemical KineticsHeat TransferPolymer ChemistryPolymer CharacterizationPolymer Physical ChemistryPolymer PhysicsPolymerization ChemistryPolymerization KineticsPolymerization Temperature EffectsPolymerization Of Vinyl MonomersPolymerization Rate ConstantsTemperature-dependent Reaction RateThermocouple InstrumentationThermocouple MeasurementThermocouple ThermometryVelocityVinyl Polymerization
Abstract To measure the rate of vinyl polymerization, a thermistor method was devised and better results were obtained compared with the thermocouple method, in the points of sensitivity of temperature, adiabatic time period, instrument’s lag in response and saving the space of the reaction vessel. The kp/kt value of styrene at 30°C obtained by this method was 2.02×10−6 and reasonable in comparison with other values obtained by different methods.
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W. I. Bengough, H. W. Melville · Proceedings of the Royal Society of London A Mathematical and Physical Sciences · 1955 · 45 citations
W. I. Bengough, H. W. Melville · Proceedings of the Royal Society of London A Mathematical and Physical Sciences · 1954 · 27 citations