Reaction of Diphenylgermane with (Ph<sub>3</sub>P)<sub>2</sub>Pt(η<sup>2</sup>-C<sub>2</sub>H<sub>4</sub>): Generation of Mono- and Dinuclear Complexes Containing Pt−Ge Bonds. X-ray Crystal Structure Determination of [(Ph<sub>3</sub>P)Pt(μ-η<sup>2</sup>-H-GePh<sub>2</sub>)]<sub>2</sub> - Concepedia

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Reaction of Diphenylgermane with (Ph<sub>3</sub>P)<sub>2</sub>Pt(η<sup>2</sup>-C<sub>2</sub>H<sub>4</sub>): Generation of Mono- and Dinuclear Complexes Containing Pt−Ge Bonds. X-ray Crystal Structure Determination of [(Ph<sub>3</sub>P)Pt(μ-η<sup>2</sup>-H-GePh<sub>2</sub>)]<sub>2</sub>

30

Citations

27

References

2005

Year

Janet Braddock‐Wilking, Joyce Y. Corey, Colin White, Huan Xu, Nigam P. Rath

Organometallics

X-ray CrystallographyInorganic ChemistryBiochemistryNatural SciencesCoordination ComplexMolecular BiologyUnusual Exchange ReactionMolecular ComplexChemistryDinuclear ComplexInorganic SynthesisInorganic Compound

Abstract

The reaction of diphenylgermane (Ph2GeH2) with (Ph3P)2Pt(η2-C2H4) provided both mononuclear (Ph3P)2Pt(H)(GePh2H) and dinuclear [(Ph3P)Pt(μ-η2-H-GePh2)]2 complexes. The structure of the dinuclear complex was determined by X-ray crystallography. The dinuclear complex could also be obtained from an unusual exchange reaction involving the unsymmetrical dinuclear complex [(Ph3P)2(H)Pt(μ-SiR2)(μ-η2-H-SiR2)Pt(PPh3)] (SiR2 = SiC20H24) with Ph2GeH2.

References

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