Single‐Side Organically Functionalized Anderson‐Type Polyoxometalates

Abstract

An unprecedented single-side trisalkoxo-substituted Anderson-type polyoxometalate (POM) was synthesized (see scheme). As confirmed by single-crystal X-ray diffraction and IR analyses, the single-side-functionalized Anderson-type POM forms interesting supramolecular assemblies, including dimers and 1D chains. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.