Journal of Chemical & Engineering Data · 1996 · 45 citations · 20 references
Vle MeasurementsEngineeringMethanolOrganic ChemistryUniquac EquationsExperimental ThermodynamicsChemistryThermodynamic ModellingChemical EngineeringFluid PropertiesMolecular ThermodynamicsGas ChromatographyBinary MixturesAnalytical ChemistryThermodynamicsEquilibrium Thermodynamic PropertyChromatographyDrug AnalysisChemical MeasurementPhysical ChemistryPhase EquilibriumMedicineChemical KineticsVle Data
Isobaric vapor−liquid equilibrium data for 2-methoxy-2-methylpropane + methanol, 2-methoxy-2-methylpropane + ethanol, methanol + 2-methoxy-2-methylbutane, ethanol + 2-methoxy-2-methylbutane, and 2-methoxy-2-methylpropane + 2-methoxy-2-methylbutane were determined at 101.32 kPa. Fredenslund et al.'s test confirmed the results to be thermodynamically consistent. The VLE data were satisfactorily correlated using the Wilson, NRTL, and UNIQUAC equations for liquid phase activity coefficients and adequately predicted using the ASOG, UNIFAC, UNIFAC−Dortmund, and UNIFAC−Lyngby group contribution methods.
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