Physical Review Letters · 1991 · 100 citations · 9 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsSolid State PhysicsSurface ScienceElectron MicroscopyPhase TransitionsSurface CrystallographySurface Phase TransitionsSurface PhysicsSurface ThermodynamicsCrystal FacetingFacetingLow-energy Electron SpectroscopyReconstruction TransitionsSilicon Surface ReconstructionStep Bunching TransitionsSurface FacetingSurface Relaxation Kinetics
We have used low-energy electron microscopy to investigate in real time the thermodynamically driven faceting of stepped Si(111) surfaces into (7\ifmmode\times\else\texttimes\fi{}7) reconstructed (111) facets and ``step bunches.'' Our data are inconsistent with the thermodynamic expectation that an isolated linear facet should grow without limit: Instead we find that the width of the (7\ifmmode\times\else\texttimes\fi{}7) reconstructed (111) facets quickly reaches a constant maximum size. We discuss the possibility that elastic relaxations caused by the facet edges are responsible for the finite facet width.
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Some Theorems on the Free Energies of Crystal Surfaces
Conyers Herring · Physical Review · 1951 · 1.6K citations
Natural Sciences, Chemistry, Physics +17