Concepedia

Pd-Catalyzed Arylation/Oxidation of Benzylic C–H Bond

Yongju Xie, Yuzhu Yang, Lehao Huang, Xunbin Zhang, Yuhong Zhang

Organic Letters · 2012 · 93 citations · 25 references

DOIFull text

Open access

Concepts

Abstract

A palladium-catalyzed benzylic C-H arylation/oxidation reaction leading to diaryl ketones has been accomplished. The indispensable role of the bidentate system is disclosed for this sequential process. This chemistry offers a direct new access to a range of diarylketones.

References

25

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

Chao‐Jun Li · Accounts of Chemical Research · 2008 · 2.7K citations

, , +14

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

Olafs Daugulis, Hien‐Quang Do, Dmitry Shabashov · Accounts of Chemical Research · 2009 · 2K citations · Full text

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

Tetsuya Satoh, Masahiro Miura · Chemistry - A European Journal · 2010 · 1.7K citations

, , +11

Highly Regioselective Arylation of sp<sup>3</sup> C−H Bonds Catalyzed by Palladium Acetate

V. G. Zaitsev, Dmitry Shabashov, Olafs Daugulis · Journal of the American Chemical Society · 2005 · 1.5K citations

Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp<sup>2</sup> and sp<sup>3</sup> Carbon−Hydrogen Bonds

Dmitry Shabashov, Olafs Daugulis · Journal of the American Chemical Society · 2010 · 893 citations · Full text