Concepedia

Catalytic Isomerization of Cyanoolefins Involved in the Adiponitrile Process. C−CN Bond Cleavage and Structure of the Nickel π-Allyl Cyanide Complex Ni(η<sup>3</sup>-1-Me-C<sub>3</sub>H<sub>4</sub>)(CN)(dppb)

Alexandra Chaumonnot, Franck Lamy, Sylviane Sabo‐Etienne, B. Donnadieu, Bruno Chaudret, Jean‐Claude Barthelat, Jean‐Christophe Galland

Organometallics · 2004 · 56 citations · 9 references

DOI

Concepts

Abstract

Isomerization of 2-methyl-3-butenenitrile to 3-pentenenitrile is catalyzed by nickel π-allyl cyanide complexes. The mechanism is supported by in situ NMR monitoring and DFT studies.

References

9

Kinetics, Thermodynamics, and Effect of BPh<sub>3</sub>on Competitive C−C and C−H Bond Activation Reactions in the Interconversion of Allyl Cyanide by [Ni(dippe)]

N.M. Brunkan, Donna M. Brestensky, William D. Jones · Journal of the American Chemical Society · 2004 · 188 citations

, , +11

Reversible Cleavage of Carbon−Carbon Bonds in Benzonitrile Using Nickel(0)

Juventino J. Garcı́a, William D. Jones · Organometallics · 2000 · 168 citations

, , +8

Steric and electronic effects in olefin hydrocyanation at Du Pont: A scientific and industrial success story

C. A. TOLMAN · Journal of Chemical Education · 1986 · 99 citations

, , +9

Electronic effects in the nickel-catalysed hydrocyanation of styrene applying chelating phosphorus ligands with large bite angles ‡

Wolfgang Goertz, Wilhelm Keim, Dieter Vogt et al. · Journal of the Chemical Society Dalton Transactions · 1998 · 90 citations · Full text

, , +16

Stereochemistry and mechanism of nickel-catalyzed hydrocyanation of olefins and conjugated dienes

J.-E. Bäckvall, Ove S. Andell · Organometallics · 1986 · 52 citations

, , +9