Advances In Physics · 1967 · 24 citations · 0 references
Natural SciencesChemistryPhysicsPhysical ChemistryTheoretical ChemistryThermodynamicsAlloy ThermodynamicsAlloysChemical ThermodynamicsEquilibrium ThermodynamicsMixing ThermodynamicsPhase EquilibriaBinary MixturesBinary Phase EquilibriaChemical Equilibrium ModelingGibbs Free Energy Of MixingLiquid Alloy ThermodynamicsMixing In Binary AlloysThermodynamic FactorsThermodynamics Of Binary Alloys
Abstract The automatic treatment of calculations of chemical equilibrium in homogeneous phases requires analytical representation of the enthalpies and entropies of mixing of the components; therefore various approaches have been investigated, including in particular an attempt to find significant models. The ‘surrounded atom’ model provides a satisfactory method of representing all the thermodynamic characteristics of mixing in binary alloys, on the basis of four adjustable parameters.