Separation Science and Technology · 1996 · 32 citations · 10 references
EngineeringChemical EngineeringChemistryPhysical ChemistrySeparation ProcessesTransport PhenomenaGas SeparationIsotope SeparationMass TransferAnalytical SeparationsDiffusion CoefficientsDiffusion TransportDiffusion-driven TransportGas Diffusion SeparationNonlinear Diffusion EquationsNonlinear Partial Differential EquationsSeparation Factor
Abstract The demand for stable isotopes in physical and chemical research and in medical diagnostics is growing, and the gas centrifuge process is able to provide large quantities of stable isotopes. A set of diffusion equations describing separation in a gas centrifuge for a multi component mixture is established. These equations involve general diffusion coefficients. Using the radial averaging method and the simplified diffusion transport vector for a multi component isotopic mixture, nonlinear partial differential equations are transformed to a set of nonlinear ordinary differential equations. An iteration method for the solution is presented. The relationship between the separation factor and the mass difference, γ ij = γ Mj o −Mi , is shown to be in agreement with both the computational and the experimental results with very high precision.
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Molecular Theory of Gases and Liquids.
O. K. Rice · Journal of the American Chemical Society · 1955 · 3.9K citations
ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY
Donald F. Othmer, Raymond E. Kirk · Chemical & Engineering News · 1978 · 2.1K citations · Full text
The theory of isotope separation
Albert L. Myerson · Journal of the Franklin Institute · 1952 · 222 citations