Concepedia

α-Amination of Nitrogen Heterocycles:  Ring-Fused Aminals

Chen Zhang, Chandra Kanta De, Rudrajit Mal, Daniel Seidel

Journal of the American Chemical Society · 2007 · 282 citations · 2 references

DOI

Concepts

Abstract

Aromatic aminoaldehydes react with cyclic amines to produce ring-fused aminals under thermal conditions. This process is applied to two-step syntheses of the quinazolinone alkaloids deoxyvasicinone and rutaecarpine.

References

2

Transition-state geometries and stereoselectivity of alkylidenecarbene addition to olefins. An experimental and theoretical investigation

Yitzhak Apeloig, Miriam Karni, Peter J. Stang et al. · Journal of the American Chemical Society · 1983 · 55 citations

, , +6

Kinetics of Bitumen‐Derived Gas Oil Upgrading Using a Commercial NiMo/Al<sub>2</sub>O<sub>3</sub> Catalyst

Christian Botchwey, Ajay K. Dalai, John Adjaye · The Canadian Journal of Chemical Engineering · 2004 · 35 citations

, , +8