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Stable, Monomeric Imides of Aluminum and Gallium: Synthesis and Characterization of [{HC(MeCDippN)2}MN-2,6-Trip2C6H3] (M=Al or Ga; Dipp=2,6-iPr2C6H3; Trip=2,4,6-iPr3C6H2)

DOI

166

Citations

23

References

2001

Year

N.J. Hardman, Chunming Cui, Herbert W. Roesky, William H. Fink, Philip P. Power
Angewandte Chemie International Edition

Abstract

A short Ga-N bond with double-bond character is displayed by the first monomeric imide of gallium, which was obtained by the reaction of [{HC(MeCDippN)<sub>2</sub> }M:] (Dipp=2,6-iPr<sub>2</sub> C<sub>6</sub> H<sub>3</sub> , M=Ga; see picture) with N<sub>3</sub> -2,6-Trip<sub>2</sub> C<sub>6</sub> H<sub>3</sub> (Trip=2,4,6-iPr<sub>3</sub> C<sub>6</sub> H<sub>2</sub> ). The analogous aluminum (M=Al) compound is also readily available.

References

YearCitations

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