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Synthesis, Structural Characterization and Mesogenic Behavior of Copper(I)n-Alkylthiolates
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1999
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Materials ScienceInorganic ChemistryCrystal StructureEngineeringCrystal MaterialBioactive MetalSurface ScienceCondensed Matter PhysicsSolid-state ChemistryOrganic ChemistryChemistryMesogenic BehaviorLamellar StructureHexagonal Columnar MesophaseCrystal FormationCrystallographyCrystal Structure DesignSolid State
A lamellar structure has been found for copper(I) thiolates in the solid state, contrary to earlier reports. On melting, a hexagonal columnar mesophase, in most cases stable within a range of 50–60 °C, is formed (see scheme).