Structure and properties of Na‐magadiite dependent on temperature

Abstract

Abstract The mechanism of the thermal behaviour of Na‐magadiite at a temperature range from 293–573 K was developed based on X‐ray diffraction, DTA, DTL, Q‐TG, and gravimetric measurements. A structure model (B RANDT et al.) previously proposed was additionally used. It is possible to show that there probably is a connection between the typical modifications of basal spacing and significant shiftings of silicate sheets. Different steps of dehydration, decrystallization and structure variations can be ascribed to the several thermal transitions. The results depend on sample treatment such as the existent or not existent solid‐water vapour interaction and the establishment of equilibrium. It seems that there is a predominance of the first mentioned influence.