A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)

E. J. Corey, P.L. Fuchs

Tetrahedron Letters

Asymmetric alkylation reactions of chiral imide enolates. A practical approach to the enantioselective synthesis of .alpha.-substituted carboxylic acid derivatives

David A. Evans, Michael D. Ennis, David J. Mathre

Journal of the American Chemical Society

EngineeringAsymmetric Alkylation ReactionsPractical ApproachAltmetric Attention ScoreOrganic Chemistry +8

Palladium- and molybdenum-catalyzed hydrostannation of alkynes. A novel access to regio- and stereodefined vinylstannanes

Hualong Zhang, F. GUIBE, G.G.A. Balavoine

The Journal of Organic Chemistry

Chemical EngineeringEngineeringNovel AccessAltmetric Attention ScoreMolybdenum-catalyzed Hydrostannation +8

Chiral synthesis via organoboranes. 7. Diastereoselective and enantioselective synthesis of erythro- and threo-.beta.-methylhomoallyl alcohols via enantiomeric (Z)- and (E)-crotylboranes

Herbert C. Brown, K. S. BHAT

Journal of the American Chemical Society

EngineeringThreo-.beta.-methylhomoallyl AlcoholsNatural SciencesDiversity-oriented SynthesisAltmetric Attention Score +12

Chiral synthesis via organoboranes. 27. Remarkably rapid and exceptionally enantioselective (approaching 100% ee) allylboration of representative aldehydes at -100.degree. under new, salt-free conditions

Uday S. Racherla, Herbert C. Brown

The Journal of Organic Chemistry

HalogenationSalt-free ConditionsEnantioselective SynthesisEngineeringBiochemistry +11

Activation of 6-endo over 5-exo hydroxy epoxide openings. Stereoselective and ring selective synthesis of tetrahydrofuran and tetrahydropyran systems

K. C. Nicolaou, C. V. C. Prasad, Patricia K. Somers, +1

Journal of the American Chemical Society

EngineeringTetrahydropyran SystemsDonut IconAltmetric Attention ScoreOrganic Chemistry +7

Enantiomeric Z- and E-crotyldiisopinocampheylboranes. Synthesis in high optical purity of all four possible stereoisomers of .beta.-methylhomoallyl alcohols

Herbert C. Brown, K. S. BHAT

Journal of the American Chemical Society

EngineeringDonut Icon.Beta.-methylhomoallyl AlcoholsEnantiomeric Z-Altmetric Attention Score +11

Gambieric acids, new potent antifungal substances with unprecedented polyether structures from a marine dinoflagellate Gambierdiscus toxicus

Hiroshi Nagai, Michio Murata, Koichiro Torigoe, +2

The Journal of Organic Chemistry

Industrial MycologyMarine BiotechnologyBioorganic ChemistryEngineeringAntifungal Agent +13

Gambieric acids: unprecedented potent antifungal substances isolated from cultures of a marine dinoflagellate Gambierdiscus toxicus

Hiroshi Nagai, Koichiro Torigoe, Masayuki Satake, +3

Journal of the American Chemical Society

Industrial MycologyMarine BiotechnologyAntifungal AgentDonut IconMedicine +8

Stereocontrolled Second Generation Syntheses of the ABC and FG Ring Systems of Brevetoxin B

K. C. Nicolaou, David A. Nugiel, Elias A. Couladouros, +1

Tetrahedron

Brevetoxin BHalogenationBiosynthesisBioorganic ChemistryFg Ring Frameworks +12