Calculational Evidence for Lack of Intermediates in the Thermal Unimolecular Vinylcyclopropane to Cyclopentene 1,3-Sigmatropic Shift

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTCalculational Evidence for Lack of Intermediates in the Thermal Unimolecular Vinylcyclopropane to Cyclopentene 1,3-Sigmatropic ShiftErnest R. Davidson and Joseph J. GajewskiView Author Information Department of Chemistry, Indiana University Bloomington, Indiana 47405 Cite this: J. Am. Chem. Soc. 1997, 119, 43, 10543–10544Publication Date (Web):October 29, 1997Publication History Received15 April 1997Revised14 July 1997Published online29 October 1997Published inissue 1 October 1997https://pubs.acs.org/doi/10.1021/ja9711932https://doi.org/10.1021/ja9711932rapid-communicationACS PublicationsCopyright © 1997 American Chemical SocietyRequest reuse permissionsArticle Views307Altmetric-Citations55LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Chemical calculations,Isomerization,Molecular structure,Potential energy,Transition states Get e-Alerts