Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases · 1989 · 31 citations · 0 references
Natural SciencesChemistryElectrochemistryPhysical ChemistryTransport PhenomenaElectrical ConductivityElectrochemical ThermodynamicsElectrolyte SolutionsHeat ConductionIon Transport In ElectrolytesIonic ConductivityAqueous Electrolyte SolutionsAssociation ConstantsAssociation EquilibriaConductivityConductivity Of Electrolyte SolutionsElectrolyte Solution ThermodynamicsPerchlorate SaltsThermodynamics Of Electrolyte Solutions
Integral heats of solution of sodium perchlorate (NaClO4) in water–tetrahydrofuran (THF) mixtures from 0 to 100 mol% THF have been measured. The electric conductivity of NaClO4 solutions in binary solvents containing from 0 to 80 mol% THF have also been measured, as have the conductivities of solutions of sodium chloride (NaCl) and sodium iodide (NaI) in mixtures containing from 0 to 35 mol% THF. Molar electro-conductivities, Walden products and association equilibria constants have been determined. Taking into account ion-pair association, standard enthalpies of solution have been recalculated.