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Temperature Dependence of Nucleation Density of Chemical Vapor Deposition Diamond
35
Citations
7
References
1992
Year
Materials ScienceDiamond-like CarbonChemical EngineeringEngineeringNucleation DensityCrystal Growth TechnologySurface ScienceApplied PhysicsNanomanufacturingTemperature DependenceNucleationThermodynamicsChemistryChemical DepositionChemical KineticsChemical Vapor DepositionEllipsometric Monitoring
The temperature dependence of the nucleation density of Chemical Vapor Deposition diamond was carefully investigated by ellipsometric monitoring. Substrates were pre-treated by rubbing with diamond powder and then by wiping off the residual powder until visually clean. Nucleation density was greater than 10 10 /cm 2 in some ranges of temperature. It was also observed that nucleation density increased suddenly to 860°C and then gradually decreased in the range of higher temperatures. The results were explained by a change in the adsorption state of the precursor, from a physical to a chemical.
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