Concepedia

Linear Pentanuclear Complexes Containing a Chain of Metal Atoms: [Co(μ<sub>5</sub>‐tpda)<sub>4</sub>(NCS)<sub>2</sub>] und [Ni(μ<sub>5</sub>‐tpda)<sub>4</sub>Cl<sub>2</sub>]

Shen‐Jye Shieh, Chin‐Cheng Chou, Gene‐Hsiang Lee, Chih‐Chieh Wang, Shie‐Ming Peng

Angewandte Chemie International Edition in English · 1997 · 176 citations · 6 references

DOI

Concepts

Abstract

Both anti–anti–anti–anti and syn–syn–syn–syn conformations of the bound metal ions are possible with the new ligand N,N′-bis(α-pyridyl)-2,6-diaminopyridine (H2tpda). Pentanuclear CoII and NiII complexes are accessible with this ligand (see sketch on the right). The metal chain is helically wrapped by four all-syn tpda ligands.

References

6

Advanced inorganic chemistry

W.J. Orville-Thomas · Journal of Molecular Structure · 1973 · 6.8K citations

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Michael F. Läppert · Journal of Organometallic Chemistry · 1993 · 1.1K citations

, , +10

Structure of a linear unsymmetrical trinuclear cobalt(<scp>II</scp>) complex with a localized CO<sup>II</sup>–CO<sup>II</sup>bond: dichlorotetrakis[µ<sub>3</sub>-bis(2-pyridyl)amido]tricobalt(<scp>II</scp>)

En‐Che Yang, Ming‐Chu Cheng, Ming‐Shih Tsai et al. · Journal of the Chemical Society Chemical Communications · 1994 · 148 citations

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Linear trinuclear three-centred metal–metal multiple bonds: synthesis and crystal structure of [M<sub>3</sub>(dpa)<sub>4</sub>Cl<sub>2</sub>][M = Ru<sup>II</sup>or Rh<sup>II</sup>, dpa = bis(2-pyridyl)amidoanion]

Jinn-Tsair Sheu, C.-C. Lin, Ito Chao et al. · Chemical Communications · 1996 · 120 citations

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Synthesis and characterization of 1,8-naphthyridine complexes of 1.5-valent nickel

Luigi Sacconi, Carlo Mealli, Dante Gatteschi · Inorganic Chemistry · 1974 · 77 citations

, , +7