Publication | Closed Access
Addition Reaction of Allylic Stannanes to the Triplet Excited State of C<sub>60</sub> via Photoinduced Electron Transfer Process Leading to Asymmetric Hybridization Chemistry for Fullerene Terpenoid
15
Citations
0
References
2004
Year
Asymmetric VersionAsymmetric CatalysisChemical EngineeringCross-coupling ReactionEngineeringPhotoredox ProcessPhotochemistrySynthetic PhotochemistryOrganic ChemistryFullereneAsymmetric Hybridization ChemistryChemistryAllylic FullerenesAllylic StannanesEnantioselective SynthesisTriplet Excited State
Addition of allylic stannanes to C60 takes place under UV-irradiation in benzene as well as benzonitrile to yield the allylic fullerenes, of which the asymmetric version with pinene-derived chiral allylic stannane leads to an enantio-pure fullerene terpenoid.