Separation Science · 1969 · 29 citations · 6 references
Natural SciencesChemical EngineeringChemistryAnalytical ChemistrySeparation ProcessesSeparation ScienceChromatographic SeparationChromatographyGelsIntermolecular ForcesIntermolecular InteractionsChromatographic Separation MechanismsIntermolecular CooperativityMolecular AssociationPolymer-solvent InteractionsSeparation MechanismsSolute-solvent InteractionsSolvent InteractionsSolvent-mediated Interactions
Abstract The effect of molecular association upon gel-permeation chromatographic separations is examined. Application of a previously established GPC elution-volume/molar-volume relationship to the study of solvent/solute interactions is discussed. The use of such interactions to improve fractionating ability of GPC columns is described. Application of the GPC technique to fundamental studies of forces involved in intermolecular association is suggested.
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Gel permeation chromatography—Part 1
Jack Cazes · Journal of Chemical Education · 1966 · 66 citations