Concepedia

Titanium Complexes with Tripodal Amido Ligands: Building Blocks for Stable Bimetallic Coordination Compounds Containing Highly Polar Metal–Metal Bonds

Stefan Friedrich, Harald Memmler, Lutz H. Gade, Wan‐Sheung Li, Mary McPartlin

Angewandte Chemie International Edition in English · 1994 · 75 citations · 21 references

DOI

Concepts

Abstract

Unsupported TiFe, TiRu, and TiCo bonds are found in the stable dinuclear compounds of type 1 (M = Fe, Ru, Co). These compounds were synthesized from the appropriate mononuclear titanium bromide complex and carbonyl metalates. The polydentate ligands on the early transition metal clearly provide the key to successful stabilization of the unsupported metal–metal bond.

References

21

Early-late heterobimetallics

Douglas W. Stephan · Coordination Chemistry Reviews · 1989 · 440 citations

Atranes: new examples with unexpected properties

John G. Verkade · Accounts of Chemical Research · 1993 · 376 citations

, , +5

Phosphinidenetantalum(<scp>V</scp>) Complexes of the Type [(N<sub>3</sub>N)TaPR] as Phospha‐Wittig Reagents

Christopher C. Cummins, Richard R. Schrock, William M. Davis · Angewandte Chemie International Edition in English · 1993 · 171 citations

, , +7

Trigonal‐Monopyramidal M<sup>III</sup> Complexes of the Type [M(N<sub>3</sub>N)] (M = Ti, V, Cr, Mn, Fe; N<sub>3</sub>N = [(<i>t</i>BuMe<sub>2</sub>Si)\documentclass{article}\usepackage{amssymb}\pagestyle{empty}\begin{document}$\mathop {\rm N}\limits^{\hbox{..}}_{\raise3pt\hbox{..}}$\end{document}CH<sub>2</sub>CH<sub>2</sub>]<sub>3</sub>N)

Christopher C. Cummins, Jenny Lee, Richard R. Schrock et al. · Angewandte Chemie International Edition in English · 1992 · 120 citations

, , +13

Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N]

Christopher C. Cummins, Richard R. Schrock, William M. Davis · Organometallics · 1992 · 118 citations

, , +8