Inorganic Chemistry · 2006 · 50 citations · 7 references
Natural SciencesChemistryMedicinal ChemistryCrystal StructureInorganic ChemistryOrganic ChemistryAb Initio MethodsCoordination ChemistryCrystal ChemistryHeterocyclic ChemistryMacrocycle SynthesisMagnetism Of Inorganic CompoundsBoron ChemistryCircular DichroismCrystal Structure AnalysisElectronic Absorption SpectraElectronic Absorption SpectroscopyElectronic Circular DichroismMagnetic Circular DichroismTime-dependent Density Functional Theory
cis-3,4-Dicyano-3-hexene undergoes cyclotrimerization with BCl3 to form the new subtriazaporphyrin chloro[hexaethylsubtriazaporphyrinato]boron(III). The hydroxo derivative of this macrocycle has also been made, and the X-ray crystal structure of the hydroxy form was determined. Electronic absorption and magnetic circular dichroism spectra of the hydroxo monomer species were interpreted using time-dependent density functional theory calculations.
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cis andtrans Forms of a Binuclear Subphthalocyanine
Takamitsu Fukuda, Jay R. Stork, Richard J. Potucek et al. · Angewandte Chemie International Edition · 2002 · 93 citations