Concepedia

Synthesis and reactions of β-diketiminato divanadium(<scp>i</scp>) inverted-sandwich complexes

Yi‐Chou Tsai, Po-Yang Wang, Kuan-Ming Lin, Shin‐An Chen, Jin‐Ming Chen

Chemical Communications · 2007 · 83 citations · 63 references

DOI

Concepts

Abstract

Reduction of VCl(2)(Nacnac) (Nacnac = HC(C(Me)NC(6)H(3)-iPr(2))(2)) with KC(8) in toluene leads to the formation of a toluene-bridged inverted-sandwich divanadium(I) complex, (mu-eta(6):eta(6)-C(7)H(8))[V(Nacnac)](2), which behaves as a source of V(Nacnac) and a multi-electron reductant in the two reactions studied in this report.

References

63

Arene-Bridged Diuranium Complexes:  Inverted Sandwiches Supported by δ Backbonding

Paula L. Diaconescu, Polly L. Arnold, Thomas A. Baker et al. · Journal of the American Chemical Society · 2000 · 328 citations

, , +6

A Terminal Ni(III)−Imide with Diverse Reactivity Pathways

E. Kogut, Heather L. Wiencko, Libei Zhang et al. · Journal of the American Chemical Society · 2005 · 323 citations

, , +7

Studies of Low-Coordinate Iron Dinitrogen Complexes

Jeremy M. Smith, A.R. Sadique, Thomas R. Cundari et al. · Journal of the American Chemical Society · 2005 · 320 citations · Full text

, , +14

Stepwise Reduction of Dinitrogen Bond Order by a Low-Coordinate Iron Complex

Jeremy M. Smith, R.J. Lachicotte, Karl A. Pittard et al. · Journal of the American Chemical Society · 2001 · 240 citations · Full text

, , +12

Structure, Reactivity, and Density Functional Theory Analysis of the Six-Electron Reductant, [(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>U]<sub>2</sub>(μ<i>-</i>η<sup>6</sup>:η<sup>6</sup>-C<sub>6</sub>H<sub>6</sub>), Synthesized via a New Mode of (C<sub>5</sub>Me<sub>5</sub>)<sub>3</sub>M Reactivity

William J. Evans, Stosh A. Kozimor, Joseph W. Ziller et al. · Journal of the American Chemical Society · 2004 · 236 citations

, , +15