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Oxidatively induced carbonyl insertion and nucleophilic cleavage reactions of alkylmetal carbonyl compounds
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1973
Year
EngineeringMethanolOrganic ChemistryChemistryChemical DerivativeChemical EngineeringCross-coupling ReactionBiochemistryRadical (Chemistry)Quantitative YieldCatalysisBiomolecular EngineeringAlkylmetal Carbonyl CompoundsNucleophilic Cleavage ReactionsInduced Carbonyl InsertionNatural SciencesMethyl EsterChemical KineticsDeoxygenationCarbonyl Metabolism
Oxidation of several alkylmetal carbonyl compounds by cerium(IV) ion in methanol takes place extremely rapidly to give the methyl ester of the next higher homologous carboxylic acid, in some cases in quantitative yield.