Total synthesis of optically active cotylenol, a fungal metabolite having a leaf growth activity. Intramolecular ene reaction for an eight-membered ring formation

The first practical method for asymmetric epoxidation

Tsutomu Katsuki, K. Barry Sharpless · Journal of the American Chemical Society · 1980 · 2.6K citations

Natural Sciences, Chemistry, Analytical Chemistry +5

Catalytic asymmetric epoxidation and kinetic resolution: modified procedures including in situ derivatization

Yun Gao, Janice M. Klunder, Robert M. Hanson et al. · Journal of the American Chemical Society · 1987 · 1.9K citations

Natural Sciences, Biochemistry, Chemistry +15

High stereo- and regioselectivities in the transition metal catalyzed epoxidations of olefinic alcohols by tert-butyl hydroperoxide

K. Barry Sharpless, Robert Michaelson · Journal of the American Chemical Society · 1973 · 739 citations

Natural Sciences, Chemistry, Catalysis +8

Grignard-type carbonyl addition of allyl halides by means of chromous salt. A chemospecific synthesis of homoallyl alcohols

Yoshitaka Okude, S. HIRANO, Tamejiro Hiyama et al. · Journal of the American Chemical Society · 1977 · 512 citations

Natural Sciences, Chemistry, Catalysis +8

The structure of fusicoccin A

A. Ballio, M. Brufani, C.G. Casinovi et al. · Cellular and Molecular Life Sciences · 1968 · 147 citations

Life Sciences, Biochemistry, Microbiology +6